Posted by
seobb on Friday, July 31, 2009 5:06:48 AM
Heat and water for example are not good for any battery. But it is
surprising to me how many people use their battery and device in both
and of course that represents several failure modes. An example is when
one of our customers several years ago always took his iPod mini into
the sauna at his gym. Well that is not the best place for a battery or
device. Eventually his battery died and so did the device. That is a
bad failure mode brought about be a user. Another example is when there
are metallic electrode shavings evident in the batteries electrolyte.
When current is running from one electrode to another through the
electrolyte the shavings cause any battery to short circuit. The short
circuiting could result in the battery smoking, bubbling or stopping.
That is an example of bad manufacturing and of course a failure effect.
Another example of a failure mode is when you open the battery casing.
If you open the casing once it is sealed hermeneutically then you run
the big risk of causing a failure mode to occur.
In any event - any failure mode will cause a battery to either
operate at a lower performance than originally designed or stop working
period. One interesting side note is that devices can operate with a
battery that is at a lower voltage (but not higher voltage) as the
device originally manufactured. The reason is because a battery's
voltage is not necessarily a static measurement.
Volts - or V - are an electrical measure of energy potential.
Voltage can also be thought of as the amount of "pressure" of electrons
that pass from a negative connector to a positive connector. Or V can
be defined as the measure of the strength of an electrical source of
power for a given current level.
Voltage can also be defined as the Electrical Potential difference -
a quantity in physics related to the amount of energy that would be
required to move an object from one place to another against various
types of force. In the fields of electronics the electrical potential
difference is the amount of work per charge needed to move electric
charge from the second point to the first, or equivalently, the amount
of work that unit charge flowing from the first point to the second can
perform.
Mathematically voltage is commonly measured by V= I x R; where V=Voltage, I=Current, R=Resistance.
Beyond the definition what challenges many is the confusion that a battery contains four unique types of voltage measurements.
Each voltage measurement type residing in a battery effects battery life.
- Float Voltage – is battery voltage at zero current (with battery disconnected).
- Nominal Voltage – is battery voltage range 3.7V, 5.2V, 10.2V, 12V
etc that says that a voltage range exists depending on the number of
cells in the battery. For example a 12 Volt battery is made of 6 cells
and has a Float voltage of about 12V.
- Charge Voltage - The voltage of a battery while charging.
- Discharge Voltage - The voltage of a battery while discharging.
Again, this voltage is determined by the charge state and the current
flowing in the battery.
So in effect it is possible that a device will operate on a battery at lower voltage. I hope this answers your question.
uestion from a reader: “How many cells are in the Toshiba
Satellite M105-S3041 Laptop Battery? The battery is for a Toshiba
Satellite M105-S3041 and its technical ratings are 10.8 volts 8800 mAh,
Lithium Ion
The question from the reader is a great question for it gets to the
heart of battery manufacturing and begins to unravel the power of a
battery. The answer is simply: 12 cells. But what does the answer mean
and how does the number of cells relate to the overall value of a
battery? Let’s find out…
What is a Battery and How Does it Create Energy?
A battery is a device that converts chemical energy into electrical
energy. Batteries have two electrodes, an anode (the negative end) and
a cathode (the positive end). Collectively the anode and the cathode
are called the electrodes. What is positve and what is the negative
terminal? It would be great to simply say that the anode is negative
and the cathode is positive, however, that is not always the case.
Somtimes the opposite is true depending on battery technology.
In between the battery’s two electrodes runs an electrical current
caused primarily from a voltage differential between the anode and
cathode. The voltage runs through a chemical called an electrolyte
(which can be either liquid or solid). This battery consisting of two
electrodes is called a voltaic cell.
Therefore batteries in effect create electrochemical energy. In
order to convert chemical energy into electrical energy there is a
chain of events that have to occur prior to the creation of electrical
energy. Key to the creation of electrochemical energy in batteries is
that electrical energy is injected into two chemicals in a solution.
Electricity is introduced into a battery via a charger. The charger
acts as a conduit of the pushing electrons that are forcing their way
into the chemical lithium. This charge process involves intercalation:
the joining of a molecule (or molecule group) between two other
molecules (or groups). Intercalation is the process of ions being
pushed by electrical current into solid lithium compounds. Lithium is
one of the chemical components used to create electrical energy in
batteries. Lithium compounds have minuscule spaces between the
crystallized planes for small ions to insert themselves from a force of
current. Ionizing lithium loads the crystal planes to the point where
they are forced into a current flow. Intercalation replenishes, in
effect, lithium but the net result of ionization is the ultimate
depletion of the lithium reactive property. You could say if you use it
you will lose it!
But what makes lithium good for batteries is that lithium is one of
the metals in the alkali group (the other metals include Sodium,
Potassium, Rubidium, Cesium, and Francium). Lithium is a highly
reactive metal. Lithium has only one electron in its outer shell (two
electrons in its inner shell), which makes it chemically “ready” to
lose that one electron in ionic bonding with other elements. Lithium is
used as a battery anode material (due to its high electrochemical
potential). Electrochemical potential is the sum of the chemical
potential and the electrical potential. The higher the electrochemical
potential the better the electrical current yields. In some
lithium-based cells the electrochemical potential can be five times
greater than an equivalent-sized lead-acid cell and three times greater
than alkaline batteries. One other core advantage that lithium has is
that it is soft and bendable which allows for tight configurations in
small cell designs (PDAs. Laptops, Cameras etc…).
What Type of Lithium Cell is Used in Laptops
Now this brings us to battery cells and our original question from
the reader. Lithium based battery cells are good but there are a
variety of lithium based battery cells. For example the lithium based
cell identified as 18650 is one of the most common battery cell on the
market for laptops. 18650 is manufactured by many manufacturers
including many private branded companies to public companies like LG,
Sony, Sanyo, Samsung, Panasonic.
18650 is a 3.6V cylindrical Li-Ion cell. 18650 has no memory effect
(distinguish between digital memory effect) and longer storage life
than NiMH battery cells. 18650 is light weight and has a high energy
density. It is in effect perfect for building batteries for laptop and
other portable power devices.
The additional technical specifications for the 18650 battery cell include:
- Nominal Voltage Average 3.7 V – the concept of nominal voltage is
that voltage range exists depending on the number of cells in the
battery.
- Nominal Capacity - 2200 mAh (above 2200 the stability of lithium based cells is called into question)
- • Max. Charging Current - 2.4 Amps Max.
- • Max. Discharging Current - 4.6 Amps max.
- • Dimensions (DxH) 18.3 mm (Max 18.4) x 64.9 mm (Max 65.1)
- • Weight 46.5 g (1.64 oz)
- Internal Impedance Internal Impedance: less or equal to 90 ohms
- Cycle Performance is 80% of initial capacity at 300 cycles
Now as stated above the reader asked how many cells were in the
Toshiba Satellite M105-S3041 Laptop Battery? The battery is rated at
10.8 volts and a capacity of 8800 mAh.
As I mentioned above the nominal voltage average is 3.7V. Some
manufacturers may use 3.6V and some may use 3.7V. In the case of a
laptop battery with 10.8V the nominal voltage rating used is 3.6V. Thus
if we divide 10.8V by 3.6V we get 3. Thus 3 cells in a series. We also
know that the batteries capacity is 8800 mAh. We know the nominal
capacity is 2200 mAh. Therefore if we divide 8800 mAh by 2200 mAh then
we get 4 in parallel.
Therefore we have 3 cells in series X 4 cells in parallel equals 12 cells in total.
Until next time - Dan Hagopian, Laptop Batteries